Metal–Organic?Framework?Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries

نویسندگان

چکیده

Metal-sulfur batteries (MSBs) are considered up-and-coming future-generation energy storage systems because of their prominent theoretical density. However, the practical applications MSBs still hampered by several critical challenges, i.e., shuttle effects, sluggish redox kinetics, and low conductivity sulfur species. Recently, benefiting from high surface area, regulated networks, molecular/atomic-level reactive sites, metal-organic frameworks (MOFs)-derived nanostructures have emerged as efficient durable multifaceted electrodes in MSBs. Herein, a timely review is presented on recent advancements designing MOF-derived electrodes, including fabricating strategies, composition management, topography control, electrochemical performance assessment. Particularly, inherent charge transfer, intrinsic polysulfide immobilization, catalytic conversion engineering MOF for systematically discussed. In end, essence how MOFs’ influence properties conclude future tendencies regarding construction exposed. It believed that this progress will provide significant experimental/theoretical guidance understanding thus offering promising orientations development fast-kinetic robust broad fields.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Fracture and debonding in lithium-ion batteries with electrodes of hollow core-shell nanostructures

In a novel design of lithium-ion batteries, hollow electrode particles coated with stiff shells are used to mitigate mechanical and chemical degradation. In particular, silicon anodes of such coreeshell nanostructures have been cycled thousands of times with little capacity fading. To reduce weight and to facilitate lithium diffusion, the shell should be thin. However, to avert fracture and deb...

متن کامل

Electrode Nanostructures in Lithium‐Based Batteries

Lithium-based batteries possessing energy densities much higher than those of the conventional batteries belong to the most promising class of future energy devices. However, there are some fundamental issues related to their electrodes which are big roadblocks in their applications to electric vehicles (EVs). Nanochemistry has advantageous roles to overcome these problems by defining new nanos...

متن کامل

Nanowire Electrodes for Advanced Lithium Batteries

*Correspondence: Liqiang Mai , State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, WUT-Harvard Joint Nano Key Laboratory, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, China e-mail: [email protected] Since the commercialization of lithium ion batteries (LIBs) in the past two decades, rechargeable LIBs have become widespread power sources for por...

متن کامل

Negative electrodes for Na-ion batteries.

Research interest in Na-ion batteries has increased rapidly because of the environmental friendliness of sodium compared to lithium. Throughout this Perspective paper, we report and review recent scientific advances in the field of negative electrode materials used for Na-ion batteries. This paper sheds light on negative electrode materials for Na-ion batteries: carbonaceous materials, oxides/p...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Advanced Materials

سال: 2021

ISSN: ['1521-4095', '0935-9648']

DOI: https://doi.org/10.1002/adma.202008784